Osmium thioselenochloride Os2S6Se2Cl8: Synthesis, cluster isolation, and structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-03

AUTHORS

S. V. Volkov, R. E. Gladyshevskii, Yu. V. Mironov, P. Yu. Demchenko, O. G. Yanko, A. I. Smolentsev, Z. A. Fokina, L. B. Khar’kova, S. A. Baranets

ABSTRACT

The quaternary thioselenochloride complex Os2S6Se2Cl8 (I) was obtained by a reaction of OsO4 with a solution of Se in S2Cl2 at 100°C and identified by combination of X-ray diffraction (polycrystalline approach) and cluster framework isolation. A reaction of complex I with melted 4-cyanopyridine (4-CNPy) at 165°C gave the complex Os2S2Cl4(4-CNPy)4, which confirms the integrity of the binuclear cluster frame-work [Cl2OsS2OsCl2] in complex I. More... »

PAGES

167-172

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328412030104

DOI

http://dx.doi.org/10.1134/s1070328412030104

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018693902


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