Binuclear copper(II) complexes with acyldihydrazones of N-benzenesulfonyl-L-aspartic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-11

AUTHORS

V. F. Shul’gin, E. A. Zamnius, A. N. Gusev, O. V. Konnik, E. B. Rusanov, V. Ya. Zub, V. V. Minin

ABSTRACT

The structure and the EPR spectra of copper(II) coordination compounds with acyldihydrazones of N-benzenesulfonyl-L-aspartic acid and salicylaldehyde (2-hydroxyacetophenone) were described. The compounds were studied by chemical and thermal analyses, IR spectroscopy, and EPR. The molecular and crystal structures of copper(II) complexes with N-benzenesulfonyl-L-aspartic acid bis(salicylidene)hydrazone (H4L1) [Cu2L1 · 2Py] · 1.5 H2O was determined by X-ray diffraction. The crystals are triclinic: a = 10.4714(4) Å, b = 12.9702(5) Å, c = 14.6187(9) Å, α = 104.763(2)°, β = 93.082(2)°, γ = 111.4240(10)°, space group P, Z = 2. The binuclear complexes containing copper cations whose coordination polyhedra are connected by an aliphatic spacer (Cu...Cu, 8.669 Å) are additionally linked by phenoxy bridges (Cu...Cu, 3.398 Å). The EPR spectra of these compounds in solutions exhibit an isotropic signal of seven HFS lines due to two equivalent copper ions with the spin Hamiltonian parameters g = 2.115−2.120, aCu = (35.5−38.0) × 10−4 cm−1, which is indicative of weak exchange interactions between the paramagnetic sites. More... »

PAGES

811

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1134/s107032841111011x

DOI

http://dx.doi.org/10.1134/s107032841111011x

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https://app.dimensions.ai/details/publication/pub.1047097334


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