Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: the crystal structure of Zn(234-MeO-Ba)2En)I2 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-08

AUTHORS

A. D. Khalaji, S. Jalali Akerdi, G. Grivani, H. Stoeckli-Evans, D. Das

ABSTRACT

New Symmetric bidentate Schiff-base ligands N,N′-bis(2,3,4-trimethoxybenzylidene)-1,2-di-aminoethane, (234-MeO-Ba)2En, and its corresponding zinc(II) and mercury(II) complexes, Zn((234-MeO-Ba)2En)I2 (I), Hg((234-MeO-Ba)2En)Cl2 (II) have been synthesized and characterized by elemental analyses (CHN), FT-IR and 1H NMR spectroscopy. The thermal behaviors of complexes were study using thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. The crystal structure of I was determined from single-crystal X-ray diffraction. The coordination polyhedron about the zinc(II) center in complex I is best described as a distorted tetrahedron. More... »

PAGES

578

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328411080045

DOI

http://dx.doi.org/10.1134/s1070328411080045

DIMENSIONS

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