Crystal structure and magnetic properties of the binuclear copper(II) complex based on 1,3-diaminopropan-2-ol N,N′-bis(3-formyl-5-tert-butylsalicylidene) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-07

AUTHORS

Yu. P. Tupolova, L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, K. Yu. Suponitskii, A. M. Ionov, V. A. Kogan

ABSTRACT

1,3-Diaminopropan-2-ol N,N′-bis(3-formyl-5-tert-butylsalicylidene) (H3L) and the binuclear copper(II) complex based on H3L, [Cu2L(CH3COO)] (I), are synthesized. The compounds are studied by IR and 1H NMR spectroscopies, magnetochemistry, and X-ray diffraction analysis. Compared to the copper(II) complexes with 1,3-diaminopropan-2-ol N,N′-bis(salicylidene), complex I is characterized by a substantial change in the structure resulting in weakening of the antiferromagnetic exchange interaction. More... »

PAGES

552-555

References to SciGraph publications

  • 2010-06. Magnetic exchange in Bi- and polynuclear complexes of transition metals with hydrazones and azomethines in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • 2010-02. Molecular design of azomethine complexes in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s1070328411070128

    DOI

    http://dx.doi.org/10.1134/s1070328411070128

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