Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene View Full Text


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Article Info

DATE

2011-03

AUTHORS

G. X. Liu, X. L. Xu, Y. Y. Xu, S. Nishihara, X. M. Ren

ABSTRACT

Two new metal-organic frameworks, namely, Cd(BDC)(Btx) · 0.25(H2O) (I) and Co3(BDC)3(Btx)4(H2O)4 (II) (H2BDC = 1,4-terephthalate acid and Btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TGA, and single crystal X-ray diffraction. Complex I exhibits a scarcely reported an eight-connected (424.64) net with dinuclear cadmium clusters as secondary building units, whereas complex II displays a three-dimensional co-ordination polymer with a rare (4,6)-connected net described by the (44.62)2(48.67) Schläfli symbol. In addition, the luminescence measurements reveal that complex I exhibits strong fluorescent emissions in the solid state at room temperature. More... »

PAGES

202-210

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328411020035

DOI

http://dx.doi.org/10.1134/s1070328411020035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049333446


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