Syntheses and structural characterization of silver(I) complexes with pyridine and carboxylate derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-01

AUTHORS

J. F. Lu, H. G. Ge, S. T. Min

ABSTRACT

Self-assembly between silver carboxylates with 2-aminopyridine derivatives give two silver(I) complexes, [[Ag(5MP)2(CNB)] · NH3 (I) and [Ag(3MP)2(HMB)] (II), where 5MP, CNB, 3MP, and HMB represent 2-amin-5-methylpyridine, 5-chloro-2-nitrobenzoate, 2-amino-3-methylpyridine, and 2-hydroxy-3-methoxybenzoate, respectively. The crystal structures of the complexes were investigated. The Ag atom in each complex is coordinated by two pyridine N atoms and weakly coordinated by a carboxylic O atom. The crystal of I is triclinic: space group P, a = 7.562(2), b = 11.708(3), c = 12.933(3) Å, α = 103.378(4)°, β = 93.910(4)°, γ = 99.001(4)°, V = 1093.7(5) Å3, Z = 2. The crystal of II is monoclinic: space group C2/c, a = 25.727(5), b = 10.274(2), c = 19.872(4) Å, β = 126.62(3)°, V = 4215.7(15) Å3, Z = 4. More... »

PAGES

36-39

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URI

http://scigraph.springernature.com/pub.10.1134/s107032841101009x

DOI

http://dx.doi.org/10.1134/s107032841101009x

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