Complex salts trans-[Rh(β-Pic)4Cl2]X (X = Cl−, ReO4−, and ClO4−): Synthesis, crystal structures, and thermal properties View Full Text


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Article Info

DATE

2010-05-26

AUTHORS

D. B. Vasil’chenko, E. Yu. Filatov, I. A. Baidina, P. E. Plyusnin, S. V. Korenev

ABSTRACT

Three novel complex salts containing the cation trans-[Rh(β-Pic)4Cl2]+ with the anions Cl− (I), ReO4− (II), and ClO4− (III) were obtained and characterized by elemental analysis, X-ray diffraction, NMR spectroscopy, and IR spectroscopy. The complex trans-[Rh(β-Pic)4Cl2]ReO4 crystallizes from DMF as a solvate in which solvent molecules fill the channels formed by the cations and anions. The thermal properties of complexes I, II, and II · DMF were examined by DTA. Final and some intermediate products of the thermolysis were isolated and characterized by physicochemical methods. More... »

PAGES

347-352

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328410050052

DOI

http://dx.doi.org/10.1134/s1070328410050052

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018053768


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