Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene-1,2-dithiolate ligand View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-03

AUTHORS

G. X. Liu, Y. Liu, S. Nishihara, X. M. Ren

ABSTRACT

Two novel ion-pair complexes, [IBzPy][Ni(Bdt)2] (I) and [IBzDMPy][Ni(Bdt)2] (II) (IBzPy = 1-(4-iodobenzyl)pyridinium, IBzDMPy = 1-(4-iodobenzyl)-3,5-dimethyl-pyridinium, and Bdt = benzene-1,2-dithiolate), have been synthesized and characterized by elemental analysis, IR, cyclic voltammetry, and X-ray single-crystal structure determination. The crystal structure determination reveals that the central Ni atoms in complexes I and II are in slightly distorted square-planar coordination environment. The cyclic voltammetric studies show that there are two oxidation peaks for complexes I and II, which are attributed to Ni(IV/III) and Ni(III/II) redox couples. More... »

PAGES

226-231

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328410030103

DOI

http://dx.doi.org/10.1134/s1070328410030103

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021843435


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