Copper complexes with N-aminotriazolethione azomethines: Structures and magnetochemical properties View Full Text


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Article Info

DATE

2010-03

AUTHORS

I. S. Vasil’chenko, A. S. Burlov, T. E. Shestakova, V. N. Ikorskii, T. A. Kuz’menko, V. G. Vlasenko, K. V. Bozhenko, L. N. Divaeva, A. S. Morkovnik, A. S. Bogomyakov, D. A. Garnovskii, A. I. Uraev, I. V. Pirog, G. S. Borodkin, A. N. Utenyshev, I. G. Borodkina, O. A. Karpov, A. A. Khrulev, I. E. Uflyand, A. D. Garnovskii, S. M. Aldoshin, V. I. Minkin

ABSTRACT

Azomethine derivatives of 4-amino-1,2,4-triazole-3-thiones (H2L) and their metal complexes were obtained. The stabilities of the ligand conformers were calculated using quantum-chemical techniques. Ab initio (B3LYP/LANL2DZ) calculations of the complexes in the lower singlet and triplet states were performed with full geometry optimization. The structures and magnetochemical properties of the chelate complexes obtained were examined over a wide temperature range. More... »

PAGES

189-197

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107032841003005x

DOI

http://dx.doi.org/10.1134/s107032841003005x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031828193


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