Synthesis and crystal structure of [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

E. A. Mainicheva, D. G. Samsonenko, O. A. Gerasko, V. P. Fedin

ABSTRACT

Crystals of the tetranuclear complex [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O are obtained by the slow evaporation of an aqueous solution of iron(III) nitrate and isonicotinic acid. According to the X-ray diffraction data, four metal atoms lie in the same plane and together with two μ3-O oxygen atoms form the fragment [Fe4(μ3-O)2]10+. The [Fe4O2(H2O)10(C5H5NCOO)4]8+ cation has been obtained and structurally characterized for the first time. More... »

PAGES

908

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328409120082

DOI

http://dx.doi.org/10.1134/s1070328409120082

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004164536


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