Heterometallic heterochalcogenmethylarsenide clusters: Synthesis, molecular structures, and thermolysis View Full Text


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Article Info

DATE

2009-02

AUTHORS

A. A. Pasynskii, S. S. Shapovalov, Zh. V. Dobrokhotova, K. A. Lysenko, S. N. Konchenko, N. A. Pushkarevskii

ABSTRACT

Reactions of the arsinechalcogenide complexes [Fe3(μ3-X)(μ3-AsCH3)(CO)9] (X = Se (Ia) or Te (Ib)) with (PPh3)2Pt(PhC≡CPh) (transmetalation reaction) and Cp2Cr2(SCME3)2S (Cp = π-C5H5) (photochemical reaction) gave the heterometallic (heterochalcogen)(methylarsine) clusters [(PPh3)2Pt(μ3-X)(μ3-AsCH3)Fe2(CO)6] (II and III, respectively), as well as Fe3(μ3-X)(μ3-AsCH3)(CO)8(C5H5)2Cr2(μ3-S)(μ2-StBu)2 (IV and V, respectively). The structures of complexes II, IV, and V were determined by X-ray diffraction analysis. Thermolysis of all the complexes yielded no metal carbides or oxides. More... »

PAGES

112-119

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Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328409020055

DOI

http://dx.doi.org/10.1134/s1070328409020055

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029709535


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