Crystal structure of rubidium cobalticyanide View Full Text


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Article Info

DATE

2009-02

AUTHORS

O. A. Sereda, H. Stöeckli-Evans, D. I. Semenishyn, O. Ya. Borovaya

ABSTRACT

The crystal structure of Rb3[Co(CN)6] was determined by X-ray diffraction analysis. The crystals are monoclinic, space group P21/c, a = 7.163(2), b = 10.601(3), c = 8.675(3) Å, β = 107.83(2)°, V = 627.1(3) Å3, Z = 2, ρcalcd = 2.497 g/cm3, R = 0.0844, wR = 0.2090 for 769 measured reflections. The coordination polyhedron of the Co atom is the regular octahedron [Co(CN)6]. The Rb(1) atoms are in the cavities of the octahedral structure; the Rb(2) atoms are in the cavities of the trigonal prisms, additional two atoms being more distant. All the cyano groups of the complex are in terminal positions. More... »

PAGES

108-111

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URI

http://scigraph.springernature.com/pub.10.1134/s1070328409020043

DOI

http://dx.doi.org/10.1134/s1070328409020043

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https://app.dimensions.ai/details/publication/pub.1026064935


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