Heterometallic complexes of Co2+, Ni2+, and Zn2+ with the [RuNO(NO2)4OH]2− anion and pyridine: Synthesis, crystal structure, and thermolysis View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-01

AUTHORS

G. A. Kostin, A. O. Borodin, Yu. V. Shubin, N. V. Kurat’eva, V. A. Emelyanov, P. E. Plyusnin, M. R. Gallyamov

ABSTRACT

Three new heteronuclear complexes [Ru(NO)(NO2)4(OH)M(Py)3] (M = Co2+, Ni2+, Zn2+) were synthesized and structurally characterized. In all compounds, the [Ru(NO)(NO2)4(OH)] fragment is coordinated to the M atom by a bridging OH and two bridging NO2 groups. The coordination environment of the metal also includes three pyridine nitrogen atoms. Thermal decomposition of cobalt and nickel complexes in an inert atmosphere yields bimetallic solid solutions. More... »

PAGES

57-64

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328409010126

DOI

http://dx.doi.org/10.1134/s1070328409010126

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025103034


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