Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] · 1.33H2O View Full Text


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Article Info

DATE

2008-08

AUTHORS

I. V. Medrish, E. V. Peresypkina, A. V. Virovets, L. B. Serezhkina

ABSTRACT

The single crystals of Rb2[(UO2)2(C2O4)2(SeO4)] · 1.33H2O were synthesized and studied by X-ray diffraction. The crystals are monoclinic, space group P21/m, Z= 2, the unit cell parameters: a = 5.6537(8), b = 18.736(3), c = 9.4535(15) Å, β = 98.440(5)°, V = 990.6(3) Å3, R1 = 0.0506. The main structural units of the crystal are infinite layers of [(UO2)2(C2O4)2(SeO4)]2−, corresponding to the crystal chemical group A2K202B2 (A = UO22+, K02 = C2O42−, B2 = SeO42−) of uranyl complexes. The uranium-containing layers are united into a three-dimensional framework through the electrostatic interactions with the outer-sphere rubidium ions and the hydrogen bonding system involving the outer-sphere water molecules. More... »

PAGES

629-634

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328408080125

DOI

http://dx.doi.org/10.1134/s1070328408080125

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000954120


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