Cu(II) complexes with 4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-08

AUTHORS

M. B. Bushuev, V. P. Krivopalov, N. V. Semikolenova, Yu. G. Shvedenkov, L. A. Sheludyakova, G. G. Moskalenko, L. G. Lavrenova, V. A. Zakharov, S. V. Larionov

ABSTRACT

The Cu(II) complexes with 4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine (L1) and 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine (L2) of the composition Cu2L1Br4 and Cu2L2A4 (A = Cl, Br), respectively, were synthesized and studied by IR and magnetochemical methods. The molecular structure of the complexes is likely to be binuclear. In the presence of cocatalysts methylaluminoxane and triisobutylaluminium, the title complexes exhibit catalytic activity in the ethylene polymerization reaction. More... »

PAGES

601-606

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107032840708009x

DOI

http://dx.doi.org/10.1134/s107032840708009x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002613438


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