Synthesis and crystal structures of [UO2(C6H4NO2)2(C6H5NO2)] and [UO2SO4(C6H5NO2)(H2O)] · H2O View Full Text


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Article Info

DATE

2007-06

AUTHORS

E. V. Grechishnikova, E. V. Peresypkina, A. V. Virovets, Yu.l N. Mikhailov, L. B. Serezhkina

ABSTRACT

The complexes [UO2(C6H4NO2)2(C6H5NO2) (I) and [UO2SO4(C6H5NO2)(H2O)] · H2O (II) were synthesized and studied by X-ray diffraction analysis. Crystals I are monoclinic: a = 7.0081(3), b = 14.9624(7), c = 9.1837(5) Å, β = 96.594(2)°, Z = 2, space group P21/m. Crystals II are triclinic: a = 6.8097(6), b = 9.3837(8), c = 10.4556(10) Å, α = 85.279(3), β = 75.434(3), γ = 69.180(3)°, Z = 2, space group . The main structural unit of crystal I is a mononuclear fragment, which belongs to the crystal chemical group AB201M1 (A = UO22+, B01 are ions of pyridine-2-carboxylic (picolinic) acid, M1 are molecules of picolinic acid) of the uranyl complexes. The main structural unit of crystal II is a chain, which belongs to the crystal chemical group AT3M21 (where T3-SO42−, M1 are water and picolinic acid molecules) of the uranyl complexes. Picolinic acid in complexes I, II was found to have a zwitterion structure. More... »

PAGES

458-465

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328407060127

DOI

http://dx.doi.org/10.1134/s1070328407060127

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031871843


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