1-amino-2-thiobenzimidazoleimines as novel ambidentate ligand systems View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-03

AUTHORS

I. S. Vasil’chenko, T. E. Shestakova, V. N. Ikorskii, T. A. Kuz’menko, V. G. Vlasenko, L. N. Divaeva, A. S. Burlov, A. I. Uraev, I. V. Pirog, G. S. Borodkin, P. B. Chepurnoi, I. G. Borodkina, O. A. Beletskii, O. A. Karpov, I. E. Uflyand, A. D. Garnovskii

ABSTRACT

Azomethine derivatives of 1-amino-2-thiobenzimidazole (H2L) were synthesized and studied by IR and 1H NMR spectroscopy. Thiobenzimidazoline tautomeric form of these compounds was found to predominate in a solid state and DMSO solution. Novel mono-and binuclear metal chelates M(HL)2 and M2L2 (M = Ni(II), Cu(II), Co(II), Zn(II), Cd(II)) were synthesized on the basis of H2L derivatives and their composition and structures were established from IR, 1H NMR, EXAFS, and magnetochemical data. The composition of coordination sphere was shown to produce no effect on ferromagnetic exchange in binuclear Cu(II) complexes. More... »

PAGES

176-183

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328407030049

DOI

http://dx.doi.org/10.1134/s1070328407030049

DIMENSIONS

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