Metal chelates with salicylidene-3-carboethoxy-4,5-dimethylthiophene derivatives as azomethine ligands of a new type View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

A. S. Burlov, E. N. Shepelenko, I. S. Vasil’chenko, A. S. Antsyshkina, G. G. Sadikov, P. V. Matuev, S. A. Nikolaevskii, G. S. Borodkin, V. S. Sergienko, V. A. Bren’, A. D. Garnovskii

ABSTRACT

New azomethine derivatives of salicylidene-3-carboethoxy-4,5-dimethylthiophene and their metal chelates are synthesized. The enolimine tautomeric form of the azomethine system of the ligand is determined from the data of 1H NMR and IR spectroscopy. According to the IR spectral data, the structures of the Co, Ni, Cu, and Zn complexes are octahedral (the structure of the nickel complex is proved by X-ray diffraction analysis), whereas the palladium chelate has a square structure. More... »

PAGES

879-884

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406120049

DOI

http://dx.doi.org/10.1134/s1070328406120049

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018268649


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