Synthesis and structure of [UO2(SeO4)(C2H4N4)2] · 0.5H2O View Full Text


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Article Info

DATE

2006-08

AUTHORS

E. V. Grechishnikova, A. V. Virovets, E. V. Peresypkina, L. B. Serezhkina

ABSTRACT

The single-crystal X-ray diffraction analysis of [UO2(SeO4)(C2H4N4)2] · 0.5H2O (I) is performed. The crystals are monoclinic: space group C2/c, Z = 8, a = 19.035(2), b = 7.1326(8), c = 21.477(2) Å, β = 109.683(4)°. The main structural units of the crystal are chains of [UO2(SeO4)(C2H4N4)2]. Compound I belongs to the crystal-chemical group AT3M21 (A = UO22+, T3 = SeO42−, M1 is a cyanoguanidine molecule) of the uranyl complexes. The chains are united into three-dimensional framework through hydrogen bonds involving the oxygen atoms of the selenate and uranyl groups, the nitrogen atoms of cyanoguanidine, and the hydrogen atoms of the cyanoguanidine or water molecules. More... »

PAGES

586-589

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406080100

DOI

http://dx.doi.org/10.1134/s1070328406080100

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032287299


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