Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O View Full Text


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Article Info

DATE

2006-04

AUTHORS

Zh. V. Akhmerkina, E. V. Peresypkina, A. V. Virovets, L. B. Serezhkina

ABSTRACT

Single crystals of Ba2[(UO2)(C2O4)2(NCS)]NCS · 7H2O were prepared and studied by X-ray diffraction. The crystals are monoclinic, space group P21/c, Z = 4, a = 13.508(5) Å, b = 12.268(4) Å, c = 14.965(5) Å, β = 115.38(1)°, V = 2240.6(13) Å3. The main structural units in the crystal are the island complex species [(UO2)(C2O4)2(NCS)]3− corresponding to the crystal chemical group AB201 M1 (A = UO22+, B01 = C2O42−, M1 = NCS−) of uranyl complexes, which are united into a three-dimensional framework through electrostatic interactions and through hydrogen bonds involving oxalate and isocyanate ions and water molecules. More... »

PAGES

297-303

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406040117

DOI

http://dx.doi.org/10.1134/s1070328406040117

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052560670


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