Magnetoactive binuclear copper(II) complexes based on β-aminovinylimines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-04

AUTHORS

A. I. Uraev, V. N. Ikorskii, M. P. Bubnov, K. A. Lysenko, V. G. Vlasenko, I. G. Borodkina, G. S. Borodkin, D. A. Garnovskii, A. D. Garnovskii

ABSTRACT

β-Aminovinylimines containing bulky substituents at the donor nitrogen atoms and copper(II) chelates based on them were synthesized. The compounds were studied by single crystal and powder X-ray diffraction, EXAFS, NMR, EPR, and UV/Vis spectroscopy, and magnetochemistry. The complexes with halide bridges exhibit a ferromagnetic type of spin-spin interaction. The metal chelate containing a phenyl substituent in the γ-position of the aminovinylimino ligand absorbs atmospheric oxygen in a methylene dichloride solution, which gives rise to a dimer with oxygen bridges exhibiting an antiferromagnetic type of spin-spin interaction. More... »

PAGES

287-296

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406040105

DOI

http://dx.doi.org/10.1134/s1070328406040105

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039232300


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