Crystal structure of (C2H7N4O)2[(UO2)2)(OH)2(C2O4)(CHO2)2] View Full Text


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Article Info

DATE

2006-03

AUTHORS

Zh. V. Akhmerkina, E. V. Peresypkina, A. V. Virovets, L. B. Serezhkina

ABSTRACT

An X-ray diffraction study of the single crystals of (C2H7N4O)2[(UO2)2(OH)2(C2O4)(CHO2)2] was carried out. The compound crystallizes in the triclinic system, space group , Z = 2, a = 5.5621(8) Å, b = 8.1489(10) Å, c = 11.8757(16) Å, α = 88.866(7)°, β = 82.204(6)°, γ = 87.378(6)°, V = 532.7(1) Å3, ρcalcd = 2.988 g/cm3. The main structural units in the crystal are the [(UO2)2(OH)2(C2O4)(CHO2)2)]2− chains corresponding to the crystal chemical group A2M22K02M21 (A = UO22+, M2 = OH−, K02 = C2O42−, M1 = CHO2−) of uranyl complexes. The chains are united into a three-dimensional framework through the electrostatic interaction and hydrogen bonds involving uranyl, oxalate, and hydroxyl groups, formate ions, and 1-carbamoylguanidinium cations. More... »

PAGES

221-225

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406030092

DOI

http://dx.doi.org/10.1134/s1070328406030092

DIMENSIONS

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