Zn complex with N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine: Synthesis, crystal structure, and vibration spectrum View Full Text


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Article Info

DATE

2006-03

AUTHORS

L. Kh. Minacheva, I. S. Ivanova, A. V. Dorokhov, A. S. Burlov, A. D. Garnovskii, V. S. Segienko, A. Yu. Tsivadze

ABSTRACT

The ZnL2 complex (I) (HL = N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine) is synthesized and studied by IR spectroscopy and X-ray diffraction analysis. The crystals are monoclinic: a = 23.139(2) Å, b = 19.931(2) Å, c = 14.604(2) Å, β = 121.20(1)°, Z = 4, space group C2/c, R = 0.751 for 766 reflections with I > 2σ(I). The Zn atom in a molecule of the complex lies on a twofold axis and is coordinated at the vertices of a distorted tetrahedron by four N atoms of two HL ligands (average Zn-N distance 2.024 Å). More... »

PAGES

166-172

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107032840603002x

DOI

http://dx.doi.org/10.1134/s107032840603002x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008790981


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