Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure View Full Text


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Article Info

DATE

2006-02

AUTHORS

E. G. Afonin, I. I. Vorontsov, S. N. Nikitin, M. Yu. Antipin

ABSTRACT

The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2·2H2O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group. More... »

PAGES

94-98

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406020035

DOI

http://dx.doi.org/10.1134/s1070328406020035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052313657


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