Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

E. G. Afonin, I. I. Vorontsov, S. N. Nikitin, M. Yu. Antipin

ABSTRACT

The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2·2H2O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group. More... »

PAGES

94-98

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328406020035

DOI

http://dx.doi.org/10.1134/s1070328406020035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052313657


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Kaluga Institute of Telemechanical Facilities, Kaluga, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Afonin", 
        "givenName": "E. G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vorontsov", 
        "givenName": "I. I.", 
        "id": "sg:person.01305257034.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305257034.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikitin", 
        "givenName": "S. N.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipin", 
        "givenName": "M. Yu.", 
        "id": "sg:person.010142146727.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c19670000019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038944279"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v91-043", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043586682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50118a055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055573447"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50158a021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055576013"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00875a043", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055754369"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-02", 
    "datePublishedReg": "2006-02-01", 
    "description": "The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2\u00b72H2O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070328406020035", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "32"
      }
    ], 
    "name": "Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure", 
    "pagination": "94-98", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f9300d05635321ac4493ab870774aa1317eca28d10b08ee1744a57690bceb859"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328406020035"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1052313657"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328406020035", 
      "https://app.dimensions.ai/details/publication/pub.1052313657"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000364_0000000364/records_72862_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070328406020035"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328406020035'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328406020035'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328406020035'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328406020035'


 

This table displays all metadata directly associated to this object as RDF triples.

97 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328406020035 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N2fae217d041c4a9085f1c325cff14728
4 schema:citation https://doi.org/10.1021/ic50118a055
5 https://doi.org/10.1021/ic50158a021
6 https://doi.org/10.1021/ja00875a043
7 https://doi.org/10.1039/c19670000019
8 https://doi.org/10.1139/v91-043
9 schema:datePublished 2006-02
10 schema:datePublishedReg 2006-02-01
11 schema:description The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2·2H2O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf Ncffe39580c774e2c9d809414d2ae94a5
16 Ne22becdf9dce401598e527ac3207a4ee
17 sg:journal.1294773
18 schema:name Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure
19 schema:pagination 94-98
20 schema:productId N07ae309daef749809b8ad44825b8c064
21 N0bbcd175961645bd90cc70dd797f3f8f
22 Nceb7039bf9a3491680eea79b643b2df8
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052313657
24 https://doi.org/10.1134/s1070328406020035
25 schema:sdDatePublished 2019-04-11T12:54
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N1994eb019059487581ee0e53a773a57a
28 schema:url http://link.springer.com/10.1134%2FS1070328406020035
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N07ae309daef749809b8ad44825b8c064 schema:name doi
33 schema:value 10.1134/s1070328406020035
34 rdf:type schema:PropertyValue
35 N0bbcd175961645bd90cc70dd797f3f8f schema:name readcube_id
36 schema:value f9300d05635321ac4493ab870774aa1317eca28d10b08ee1744a57690bceb859
37 rdf:type schema:PropertyValue
38 N1994eb019059487581ee0e53a773a57a schema:name Springer Nature - SN SciGraph project
39 rdf:type schema:Organization
40 N2fae217d041c4a9085f1c325cff14728 rdf:first Nca377d84fdaa4808bd18623f5ca4c08f
41 rdf:rest Nff3b7946f79b4daa93a990270939ee84
42 N6a48dfc17f1d47bc87ad70b9bfd2a790 rdf:first Nff03a9912b1247ea8d83ae17e3f925e1
43 rdf:rest Nc8fbc17103384a0ca89b6ab9c3650f4d
44 Nc8fbc17103384a0ca89b6ab9c3650f4d rdf:first sg:person.010142146727.55
45 rdf:rest rdf:nil
46 Nca377d84fdaa4808bd18623f5ca4c08f schema:affiliation Nf06f08aef2d3410ca95c97f026967e59
47 schema:familyName Afonin
48 schema:givenName E. G.
49 rdf:type schema:Person
50 Nceb7039bf9a3491680eea79b643b2df8 schema:name dimensions_id
51 schema:value pub.1052313657
52 rdf:type schema:PropertyValue
53 Ncffe39580c774e2c9d809414d2ae94a5 schema:issueNumber 2
54 rdf:type schema:PublicationIssue
55 Ne22becdf9dce401598e527ac3207a4ee schema:volumeNumber 32
56 rdf:type schema:PublicationVolume
57 Nf06f08aef2d3410ca95c97f026967e59 schema:name Kaluga Institute of Telemechanical Facilities, Kaluga, Russia
58 rdf:type schema:Organization
59 Nff03a9912b1247ea8d83ae17e3f925e1 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
60 schema:familyName Nikitin
61 schema:givenName S. N.
62 rdf:type schema:Person
63 Nff3b7946f79b4daa93a990270939ee84 rdf:first sg:person.01305257034.82
64 rdf:rest N6a48dfc17f1d47bc87ad70b9bfd2a790
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
69 schema:name Inorganic Chemistry
70 rdf:type schema:DefinedTerm
71 sg:journal.1294773 schema:issn 1070-3284
72 1608-3318
73 schema:name Russian Journal of Coordination Chemistry
74 rdf:type schema:Periodical
75 sg:person.010142146727.55 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Antipin
77 schema:givenName M. Yu.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55
79 rdf:type schema:Person
80 sg:person.01305257034.82 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
81 schema:familyName Vorontsov
82 schema:givenName I. I.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305257034.82
84 rdf:type schema:Person
85 https://doi.org/10.1021/ic50118a055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055573447
86 rdf:type schema:CreativeWork
87 https://doi.org/10.1021/ic50158a021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055576013
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1021/ja00875a043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055754369
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1039/c19670000019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038944279
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1139/v91-043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043586682
94 rdf:type schema:CreativeWork
95 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
96 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
97 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...