Kinetics of Pu(VI) Reduction with Diformylhydrazine in Nitric Acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-11

AUTHORS

K. N. Dvoeglazov, E. Yu. Pavlyukevich, P. V. Mitrikas

ABSTRACT

The kinetics of the Pu(VI) reduction with diformylhydrazine in a nitric acid medium was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO3 concentration. The reaction order with respect to Pu, diformylhydrazine, and HNO3 is 1, 1.3, and–1.5, respectively. The activation energy of the reaction is 86.9 kJ mol–1. More... »

PAGES

588-594

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362218060048

DOI

http://dx.doi.org/10.1134/s1066362218060048

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110910881


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