Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid View Full Text


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Article Info

DATE

2018-11

AUTHORS

K. N. Dvoeglazov, E. Yu. Pavlyukevich, P. V. Mitrikas

ABSTRACT

The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO3 concentration. The reaction order with respect to Np, diformylhydrazine, and HNO3 is 1, 1.3, and–1.55, respectively. The activation energy of the reaction is 85 ± 10 kJ mol–1. More... »

PAGES

581-587

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362218060036

DOI

http://dx.doi.org/10.1134/s1066362218060036

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110910880


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