Ontology type: schema:ScholarlyArticle
2018-05
AUTHORSV. V. Kalistratova, A. V. Rodin, A. S. Emel’yanov, V. L. Vidanov, V. V. Milyutin, E. V. Belova, O. V. Shmidt, B. F. Myasoedov
ABSTRACTThermal degradation of VP-1AP anion-exchange resin in the nitrate form was studied by DSC–TG. The degradation occurs in steps and is accompanied by exothermic effects in the temperature ranges 170–190, 200–280, 280–390, and 400–550°С. The first two exothermic peaks are associated with thermal degradation of the sorbent, and all the other peaks, with oxidation of the matrix with atmospheric oxygen. The kinetic parameters of separate steps were determined. A mathematical model of degradation of VP-1AP anion-exchange resin in the nitrate form was developed. It can be applied to evaluation of the safety in handling this form of the sorbent. Principal possibility of constructing a kinetic model of degradation of ion-exchange materials on the basis of the results of DSC–TG experiments performed with milligram amounts of samples, applicable to simulation of enlarged installations, was demonstrated. An experimental cell suitable for ion-exchange materials was developed for validation of the degradation kinetic models constructed on the basis of the DSC data. The thermal explosion of VP-1AP in the nitrate form in the experimental cell is observed at a thermostat temperature of 245°С, but is not observed up to 230°С. The calculated critical temperature of thermal explosion of VP-1AP anion-exchange resin in the nitrate form under the experimental conditions is in the interval 237–242°С. More... »
PAGES287-293
http://scigraph.springernature.com/pub.10.1134/s1066362218030104
DOIhttp://dx.doi.org/10.1134/s1066362218030104
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1104424794
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Kalistratova",
"givenName": "V. V.",
"id": "sg:person.011266034114.10",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011266034114.10"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia",
"Scientific and Engineering Centre for Nuclear and Radiation Safety, ul. Malaya Krasnosel\u2019skaya 2/8, korp. 5, 107140, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Rodin",
"givenName": "A. V.",
"id": "sg:person.015327533231.92",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015327533231.92"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Scientific and Engineering Centre for Nuclear and Radiation Safety, ul. Malaya Krasnosel\u2019skaya 2/8, korp. 5, 107140, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Emel\u2019yanov",
"givenName": "A. S.",
"type": "Person"
},
{
"affiliation": {
"name": [
"Bochvar High-Tech Research Institute of Inorganic Materials, ul. Rogova 5a, 123098, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Vidanov",
"givenName": "V. L.",
"id": "sg:person.016346537223.31",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016346537223.31"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Milyutin",
"givenName": "V. V.",
"id": "sg:person.015155076223.72",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015155076223.72"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Belova",
"givenName": "E. V.",
"id": "sg:person.010731245602.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010731245602.23"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Bochvar High-Tech Research Institute of Inorganic Materials, ul. Rogova 5a, 123098, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Shmidt",
"givenName": "O. V.",
"id": "sg:person.010662354427.70",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010662354427.70"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Myasoedov",
"givenName": "B. F.",
"id": "sg:person.01207500637.58",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/j.egypro.2014.11.861",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023615770"
],
"type": "CreativeWork"
}
],
"datePublished": "2018-05",
"datePublishedReg": "2018-05-01",
"description": "Thermal degradation of VP-1AP anion-exchange resin in the nitrate form was studied by DSC\u2013TG. The degradation occurs in steps and is accompanied by exothermic effects in the temperature ranges 170\u2013190, 200\u2013280, 280\u2013390, and 400\u2013550\u00b0\u0421. The first two exothermic peaks are associated with thermal degradation of the sorbent, and all the other peaks, with oxidation of the matrix with atmospheric oxygen. The kinetic parameters of separate steps were determined. A mathematical model of degradation of VP-1AP anion-exchange resin in the nitrate form was developed. It can be applied to evaluation of the safety in handling this form of the sorbent. Principal possibility of constructing a kinetic model of degradation of ion-exchange materials on the basis of the results of DSC\u2013TG experiments performed with milligram amounts of samples, applicable to simulation of enlarged installations, was demonstrated. An experimental cell suitable for ion-exchange materials was developed for validation of the degradation kinetic models constructed on the basis of the DSC data. The thermal explosion of VP-1AP in the nitrate form in the experimental cell is observed at a thermostat temperature of 245\u00b0\u0421, but is not observed up to 230\u00b0\u0421. The calculated critical temperature of thermal explosion of VP-1AP anion-exchange resin in the nitrate form under the experimental conditions is in the interval 237\u2013242\u00b0\u0421.",
"genre": "research_article",
"id": "sg:pub.10.1134/s1066362218030104",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1345524",
"issn": [
"1066-3622",
"1608-3288"
],
"name": "Radiochemistry",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "60"
}
],
"name": "Kinetics of Thermal Degradation of VP-1AP Anion-Exchange Resin in the Nitrate Form",
"pagination": "287-293",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"4a7b6bf53de1f6951c7e0644fa846552bbbbe5d346fb910e05ddee99dca269b7"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1066362218030104"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1104424794"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1066362218030104",
"https://app.dimensions.ai/details/publication/pub.1104424794"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T00:26",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000570.jsonl",
"type": "ScholarlyArticle",
"url": "https://link.springer.com/10.1134%2FS1066362218030104"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1066362218030104'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1066362218030104'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1066362218030104'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1066362218030104'
This table displays all metadata directly associated to this object as RDF triples.
119 TRIPLES
21 PREDICATES
28 URIs
19 LITERALS
7 BLANK NODES