Thermal stability of irradiated solutions of 2,2′-bipyridine-6,6′-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in fluorinated sulfones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-11

AUTHORS

I. V. Skvortsov, E. V. Belova, A. V. Rodin, N. E. Borisova, A. V. Ivanov, B. F. Myasoedov

ABSTRACT

The effect exerted by irradiation with accelerated electrons on the thermolysis kinetics in two-phase systems consisting of 14 M aqueous HNO3 and FS-13 diluent or 0.1 M solution of 2,2′-bipyridine-6,6′-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in FS-13 was determined. Samples were irradiated at an electron accelerator at a dose rate of 10 kGy h–1 to integral doses of 0.1, 0.5, and 1 MGy. The mixtures were heated in an autoclave at 170 and 200°С. A study of the heat and gas evolution processes occurring in the course of thermolysis of extraction mixtures irradiated to doses of 1 MGy showed that conditions for the development of autocatalytic oxidation are not created even in the systems kept for 2 weeks in contact with 14 M HNO3. More... »

PAGES

607-611

Journal

TITLE

Radiochemistry

ISSUE

6

VOLUME

59

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s106636221706008x

DOI

http://dx.doi.org/10.1134/s106636221706008x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1099695399


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0402", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Geochemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Earth Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Skvortsov", 
        "givenName": "I. V.", 
        "id": "sg:person.012751006731.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012751006731.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia", 
            "Scientific and Technical Center for Nuclear and Radiation Safety, ul. Malaya Krasnosel\u2019skaya 2/8, korp. 5, 107140, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belova", 
        "givenName": "E. V.", 
        "id": "sg:person.010731245602.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010731245602.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Scientific and Technical Center for Nuclear and Radiation Safety, ul. Malaya Krasnosel\u2019skaya 2/8, korp. 5, 107140, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rodin", 
        "givenName": "A. V.", 
        "id": "sg:person.015327533231.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015327533231.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borisova", 
        "givenName": "N. E.", 
        "id": "sg:person.010522066034.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010522066034.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Moscow State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ivanov", 
        "givenName": "A. V.", 
        "id": "sg:person.07774204372.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07774204372.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Myasoedov", 
        "givenName": "B. F.", 
        "id": "sg:person.01207500637.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.mencom.2008.11.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000904351"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-012-0124-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002460192", 
          "https://doi.org/10.1007/s11172-012-0124-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1081/sei-100001370", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013562838"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/07366299.2012.735528", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018768434"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10967-014-3657-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019080366", 
          "https://doi.org/10.1007/s10967-014-3657-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/07366290701634438", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022884099"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10967-011-1070-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029044214", 
          "https://doi.org/10.1007/s10967-011-1070-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/07366299.2013.833783", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030221766"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10967-011-1179-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035092118", 
          "https://doi.org/10.1007/s10967-011-1179-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/01496390802121636", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046832423"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2010.03.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048308818"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1022353014980", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050320473", 
          "https://doi.org/10.1023/a:1022353014980"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1557/adv.2016.654", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067966087"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-11", 
    "datePublishedReg": "2017-11-01", 
    "description": "The effect exerted by irradiation with accelerated electrons on the thermolysis kinetics in two-phase systems consisting of 14 M aqueous HNO3 and FS-13 diluent or 0.1 M solution of 2,2\u2032-bipyridine-6,6\u2032-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in FS-13 was determined. Samples were irradiated at an electron accelerator at a dose rate of 10 kGy h\u20131 to integral doses of 0.1, 0.5, and 1 MGy. The mixtures were heated in an autoclave at 170 and 200\u00b0\u0421. A study of the heat and gas evolution processes occurring in the course of thermolysis of extraction mixtures irradiated to doses of 1 MGy showed that conditions for the development of autocatalytic oxidation are not created even in the systems kept for 2 weeks in contact with 14 M HNO3.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s106636221706008x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1345524", 
        "issn": [
          "1066-3622", 
          "1608-3288"
        ], 
        "name": "Radiochemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "59"
      }
    ], 
    "name": "Thermal stability of irradiated solutions of 2,2\u2032-bipyridine-6,6\u2032-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in fluorinated sulfones", 
    "pagination": "607-611", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "4ea65f45e13cc52e970c773c1bbae48584e212cb7567c85f0efb59b280c8da1b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s106636221706008x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1099695399"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s106636221706008x", 
      "https://app.dimensions.ai/details/publication/pub.1099695399"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T18:16", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8675_00000493.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S106636221706008X"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s106636221706008x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s106636221706008x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s106636221706008x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s106636221706008x'


 

This table displays all metadata directly associated to this object as RDF triples.

146 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s106636221706008x schema:about anzsrc-for:04
2 anzsrc-for:0402
3 schema:author N11e9e7a72dc64778928b00f3384300bf
4 schema:citation sg:pub.10.1007/s10967-011-1070-6
5 sg:pub.10.1007/s10967-011-1179-7
6 sg:pub.10.1007/s10967-014-3657-1
7 sg:pub.10.1007/s11172-012-0124-4
8 sg:pub.10.1023/a:1022353014980
9 https://doi.org/10.1016/j.mencom.2008.11.018
10 https://doi.org/10.1016/j.poly.2010.03.021
11 https://doi.org/10.1080/01496390802121636
12 https://doi.org/10.1080/07366290701634438
13 https://doi.org/10.1080/07366299.2012.735528
14 https://doi.org/10.1080/07366299.2013.833783
15 https://doi.org/10.1081/sei-100001370
16 https://doi.org/10.1557/adv.2016.654
17 schema:datePublished 2017-11
18 schema:datePublishedReg 2017-11-01
19 schema:description The effect exerted by irradiation with accelerated electrons on the thermolysis kinetics in two-phase systems consisting of 14 M aqueous HNO3 and FS-13 diluent or 0.1 M solution of 2,2′-bipyridine-6,6′-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in FS-13 was determined. Samples were irradiated at an electron accelerator at a dose rate of 10 kGy h–1 to integral doses of 0.1, 0.5, and 1 MGy. The mixtures were heated in an autoclave at 170 and 200°С. A study of the heat and gas evolution processes occurring in the course of thermolysis of extraction mixtures irradiated to doses of 1 MGy showed that conditions for the development of autocatalytic oxidation are not created even in the systems kept for 2 weeks in contact with 14 M HNO3.
20 schema:genre research_article
21 schema:inLanguage en
22 schema:isAccessibleForFree false
23 schema:isPartOf N94e6e2d628a54ba0b18c6bbcb0d39f75
24 Na7d60d57b83948d2896b734213b57050
25 sg:journal.1345524
26 schema:name Thermal stability of irradiated solutions of 2,2′-bipyridine-6,6′-dicarboxylic acid bis(N-ethyl-4-hexylanilide) in fluorinated sulfones
27 schema:pagination 607-611
28 schema:productId N0419f39f6e244449a85578fe7165641d
29 N2497f7058d0a48a2920f6224629e0973
30 N28fc459f59484c50be8ca07663d2f78e
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1099695399
32 https://doi.org/10.1134/s106636221706008x
33 schema:sdDatePublished 2019-04-10T18:16
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher Ned0297ab8a3d40a193012ec4023a7029
36 schema:url http://link.springer.com/10.1134/S106636221706008X
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N0419f39f6e244449a85578fe7165641d schema:name doi
41 schema:value 10.1134/s106636221706008x
42 rdf:type schema:PropertyValue
43 N11e9e7a72dc64778928b00f3384300bf rdf:first sg:person.012751006731.24
44 rdf:rest Ncd9577a6044a4a30830f324ec5b52612
45 N2497f7058d0a48a2920f6224629e0973 schema:name readcube_id
46 schema:value 4ea65f45e13cc52e970c773c1bbae48584e212cb7567c85f0efb59b280c8da1b
47 rdf:type schema:PropertyValue
48 N28fc459f59484c50be8ca07663d2f78e schema:name dimensions_id
49 schema:value pub.1099695399
50 rdf:type schema:PropertyValue
51 N42d32bab7f0f44b79938f04b43c89850 rdf:first sg:person.07774204372.49
52 rdf:rest Nf16a3b4f50f5442884b3638972189716
53 N93f8e02cf508419fb6b4bce9c7f81965 rdf:first sg:person.015327533231.92
54 rdf:rest N9b7fa67d05894da5adadb056511343a5
55 N94e6e2d628a54ba0b18c6bbcb0d39f75 schema:issueNumber 6
56 rdf:type schema:PublicationIssue
57 N9b7fa67d05894da5adadb056511343a5 rdf:first sg:person.010522066034.76
58 rdf:rest N42d32bab7f0f44b79938f04b43c89850
59 Na7d60d57b83948d2896b734213b57050 schema:volumeNumber 59
60 rdf:type schema:PublicationVolume
61 Nbcc06440f2734c22a4d2724a6de59820 schema:name Scientific and Technical Center for Nuclear and Radiation Safety, ul. Malaya Krasnosel’skaya 2/8, korp. 5, 107140, Moscow, Russia
62 rdf:type schema:Organization
63 Ncd9577a6044a4a30830f324ec5b52612 rdf:first sg:person.010731245602.23
64 rdf:rest N93f8e02cf508419fb6b4bce9c7f81965
65 Ned0297ab8a3d40a193012ec4023a7029 schema:name Springer Nature - SN SciGraph project
66 rdf:type schema:Organization
67 Nf16a3b4f50f5442884b3638972189716 rdf:first sg:person.01207500637.58
68 rdf:rest rdf:nil
69 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
70 schema:name Earth Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0402 schema:inDefinedTermSet anzsrc-for:
73 schema:name Geochemistry
74 rdf:type schema:DefinedTerm
75 sg:journal.1345524 schema:issn 1066-3622
76 1608-3288
77 schema:name Radiochemistry
78 rdf:type schema:Periodical
79 sg:person.010522066034.76 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
80 schema:familyName Borisova
81 schema:givenName N. E.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010522066034.76
83 rdf:type schema:Person
84 sg:person.010731245602.23 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
85 schema:familyName Belova
86 schema:givenName E. V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010731245602.23
88 rdf:type schema:Person
89 sg:person.01207500637.58 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
90 schema:familyName Myasoedov
91 schema:givenName B. F.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58
93 rdf:type schema:Person
94 sg:person.012751006731.24 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
95 schema:familyName Skvortsov
96 schema:givenName I. V.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012751006731.24
98 rdf:type schema:Person
99 sg:person.015327533231.92 schema:affiliation Nbcc06440f2734c22a4d2724a6de59820
100 schema:familyName Rodin
101 schema:givenName A. V.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015327533231.92
103 rdf:type schema:Person
104 sg:person.07774204372.49 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
105 schema:familyName Ivanov
106 schema:givenName A. V.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07774204372.49
108 rdf:type schema:Person
109 sg:pub.10.1007/s10967-011-1070-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029044214
110 https://doi.org/10.1007/s10967-011-1070-6
111 rdf:type schema:CreativeWork
112 sg:pub.10.1007/s10967-011-1179-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035092118
113 https://doi.org/10.1007/s10967-011-1179-7
114 rdf:type schema:CreativeWork
115 sg:pub.10.1007/s10967-014-3657-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019080366
116 https://doi.org/10.1007/s10967-014-3657-1
117 rdf:type schema:CreativeWork
118 sg:pub.10.1007/s11172-012-0124-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002460192
119 https://doi.org/10.1007/s11172-012-0124-4
120 rdf:type schema:CreativeWork
121 sg:pub.10.1023/a:1022353014980 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050320473
122 https://doi.org/10.1023/a:1022353014980
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1016/j.mencom.2008.11.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000904351
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1016/j.poly.2010.03.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048308818
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1080/01496390802121636 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046832423
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1080/07366290701634438 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022884099
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1080/07366299.2012.735528 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018768434
133 rdf:type schema:CreativeWork
134 https://doi.org/10.1080/07366299.2013.833783 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030221766
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1081/sei-100001370 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013562838
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1557/adv.2016.654 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067966087
139 rdf:type schema:CreativeWork
140 https://www.grid.ac/institutes/grid.14476.30 schema:alternateName Moscow State University
141 schema:name Moscow State University, Moscow, Russia
142 rdf:type schema:Organization
143 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
144 schema:name Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, 119071, Moscow, Russia
145 Scientific and Technical Center for Nuclear and Radiation Safety, ul. Malaya Krasnosel’skaya 2/8, korp. 5, 107140, Moscow, Russia
146 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...