Exothermic processes in mixtures of TBP with nitric acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-09

AUTHORS

E. R. Nazin, G. M. Zachinyaev, E. V. Belova, G. P. Tkhorzhnitskii, B. F. Myasoedov

ABSTRACT

Causes of initiation of exothermic self-accelerating oxidation processes in mixtures of TBP with HNO3 are analyzed. The main condition is heating of the mixtures to temperatures (Тst) above which the heat release in the chemical reaction starts to exceed the heat removal from the system. After the initiation of selfaccelerating exothermic reactions, their development and intensity depend on whether the vessels are sealed, on the HNO3 concentration, and on the heating time. Heat treatment and radiolysis of the extractant slightly decrease Тst of its mixtures with HNO3 compared to the values for the “fresh” extractant. More... »

PAGES

512-519

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362217050125

DOI

http://dx.doi.org/10.1134/s1066362217050125

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1092337355


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