Ontology type: schema:ScholarlyArticle
2014-05
AUTHORSYu. M. Kulyako, S. A. Perevalov, T. I. Trofimov, M. D. Samsonov, S. E. Vinokurov, D. A. Malikov, B. F. Myasoedov
ABSTRACTDissolution of ceramic UO2 in aqueous Fe(NO3)3 solutions at different temperatures under the conditions of limited contact with air and in the autoclave mode was studied. In the course of UO2 dissolution at 60–90°C, the U/Fe molar ratio appears to be ∼1, whereas at room temperature (25°C) this value is ∼0.5. By varying the acidity of Fe nitrate solutions at these temperatures, it is possible to increase the U/Fe molar ratio to ∼4 and to obtain uranyl nitrate solutions with simultaneous removal of Fe from the solution in the form of a precipitate of the basic salt, or to perform quantitative dissolution of UO2 under the conditions excluding the formation of such precipitate. In the course of dissolution of ceramic UO2 in Fe(NO3)3 solutions, the appearance or absence of Fe(II) ions, the formation or absence of the precipitate of the Fe basic salt, and variation of solution pH are interrelated and are determined by the process temperature. More... »
PAGES247-251
http://scigraph.springernature.com/pub.10.1134/s1066362214030059
DOIhttp://dx.doi.org/10.1134/s1066362214030059
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1052589732
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Kulyako",
"givenName": "Yu. M.",
"id": "sg:person.011727622146.20",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011727622146.20"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Perevalov",
"givenName": "S. A.",
"id": "sg:person.016136377041.89",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016136377041.89"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Trofimov",
"givenName": "T. I.",
"id": "sg:person.012337060065.95",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337060065.95"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Samsonov",
"givenName": "M. D.",
"id": "sg:person.013133732575.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013133732575.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Vinokurov",
"givenName": "S. E.",
"id": "sg:person.014523414565.96",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014523414565.96"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Malikov",
"givenName": "D. A.",
"id": "sg:person.011464650714.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011464650714.23"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Myasoedov",
"givenName": "B. F.",
"id": "sg:person.01207500637.58",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1023/b:aten.0000038094.56394.e6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008882828",
"https://doi.org/10.1023/b:aten.0000038094.56394.e6"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1014811604126",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021235393",
"https://doi.org/10.1023/a:1014811604126"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1066362211060075",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029300214",
"https://doi.org/10.1134/s1066362211060075"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1066362210040028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039851738",
"https://doi.org/10.1134/s1066362210040028"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1066362210040028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039851738",
"https://doi.org/10.1134/s1066362210040028"
],
"type": "CreativeWork"
}
],
"datePublished": "2014-05",
"datePublishedReg": "2014-05-01",
"description": "Dissolution of ceramic UO2 in aqueous Fe(NO3)3 solutions at different temperatures under the conditions of limited contact with air and in the autoclave mode was studied. In the course of UO2 dissolution at 60\u201390\u00b0C, the U/Fe molar ratio appears to be \u223c1, whereas at room temperature (25\u00b0C) this value is \u223c0.5. By varying the acidity of Fe nitrate solutions at these temperatures, it is possible to increase the U/Fe molar ratio to \u223c4 and to obtain uranyl nitrate solutions with simultaneous removal of Fe from the solution in the form of a precipitate of the basic salt, or to perform quantitative dissolution of UO2 under the conditions excluding the formation of such precipitate. In the course of dissolution of ceramic UO2 in Fe(NO3)3 solutions, the appearance or absence of Fe(II) ions, the formation or absence of the precipitate of the Fe basic salt, and variation of solution pH are interrelated and are determined by the process temperature.",
"genre": "research_article",
"id": "sg:pub.10.1134/s1066362214030059",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1345524",
"issn": [
"1066-3622",
"1608-3288"
],
"name": "Radiochemistry",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "56"
}
],
"name": "Factors governing the efficiency of dissolution of UO2 ceramic pellets in aqueous solutions of iron nitrate",
"pagination": "247-251",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"fa807d8fcab8e79203b846a4486950804fe3e1ea8f27d8ab8900f5c0649bf947"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1066362214030059"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1052589732"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1066362214030059",
"https://app.dimensions.ai/details/publication/pub.1052589732"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T20:46",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000508.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1134%2FS1066362214030059"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1066362214030059'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1066362214030059'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1066362214030059'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1066362214030059'
This table displays all metadata directly associated to this object as RDF triples.
119 TRIPLES
21 PREDICATES
31 URIs
19 LITERALS
7 BLANK NODES