A spectrophotometric study of the reduction of Pu(VIII) and Pu(VII) in alkaline solutions View Full Text


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Article Info

DATE

2014-05

AUTHORS

M. V. Nikonov, B. F. Myasoedov

ABSTRACT

The reduction of Pu(VIII) with water in ozonized 15 and 6 MNaOH solutions after termination of the ozone bubbling was studied by spectrophotometry. Kinetic curves reflecting the whole set of processes that occur in NaOH solutions of different concentrations were obtained. Calculations performed with the experimental curves made it possible to construct the kinetic curves describing the behavior of plutonium in higher oxidation states in solution and to obtain the individual absorption spectra of Pu(VII) and Pu(VIII). The processes occurring in ozonized solutions of Pu(VI) in 6 and 15 M NaOH after termination of the ozone bubbling were found to occur by different mechanisms, yielding in 4 days Pu(VI) and Pu(V), respectively. More... »

PAGES

227-234

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362214030011

DOI

http://dx.doi.org/10.1134/s1066362214030011

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004202253


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