Mathematical description of the extraction of impurity acids with tributyl phosphate in diluent and of the coextraction of the acid ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

E. A. Puzikov, B. Ya. Zilberman, Yu. S. Fedorov, I. V. Blazheva, Yu. V. Palenik, A. S. Kudinov, N. D. Goletskii, D. V. Ryabkov

ABSTRACT

The distribution of pertechnetic, permanganic, chromic, oxalic, acetic, formic, hydrazoic, nitrous, hydrofluoric, and hydrochloric acids and of hydrogen peroxide is considered within the framework of a new approach to modeling of extraction equilibria involving tributyl phosphate (TBP) in diluent. The approach is similar to that used for describing the extraction of nitric acid. Namely, the formation of solvates with TBP and the dissolution of the acids in water present in the organic phase are considered. Possible dissociation and dimerization of acids in both phases and association with the nitric acid-TBP monosolvate are taken into account. The coextraction of acid anions with uranyl is described taking into account the anion exchange and complexation with acid anions in the organic phase, with such complexation also occurring in the aqueous phase. A system of 16 equations with concentration constants or experimental equilibrium parameters is suggested for describing the extraction of impurity acids and coextraction of their anions. More... »

PAGES

167-172

Journal

TITLE

Radiochemistry

ISSUE

2

VOLUME

56

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362214020076

DOI

http://dx.doi.org/10.1134/s1066362214020076

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010783961


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