Uranium(VI) complex with m-hydroxybenzoic acid. Synthesis, crystal structure, and spectral properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

A. A. Levtsova, G. B. Andreev, N. A. Budantseva, I. G. Tananaev, B. F. Myasoedov

ABSTRACT

A new U(VI) compound with m-hydroxybenzoic acid, HIm[(UO2)(C7H5O3)3]·2H2O, was prepared. Its structure was determined by X-ray diffraction analysis and confirmed by the visible and IR spectra. The coordination number of the U atom is 8, with the hydroxyl O atom not involved in coordination with the metal ion. The main structural constituents of the compound are [(UO2)(C7H5O3)3]− anions formed by the sixcoordinate uranyl ion and three hydroxybenzoate ions acting as bidentate ligands. The imidazolium cations participate in hydrogen bonding, linking the adjacent [(UO2)(C7H5O3)3]− anions. The compound contains water molecules of crystallization, also participating in H bonding. More... »

PAGES

145-149

Journal

TITLE

Radiochemistry

ISSUE

2

VOLUME

56

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362214020039

DOI

http://dx.doi.org/10.1134/s1066362214020039

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029020673


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