Uranium(VI) complex with m-hydroxybenzoic acid. Synthesis, crystal structure, and spectral properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

A. A. Levtsova, G. B. Andreev, N. A. Budantseva, I. G. Tananaev, B. F. Myasoedov

ABSTRACT

A new U(VI) compound with m-hydroxybenzoic acid, HIm[(UO2)(C7H5O3)3]·2H2O, was prepared. Its structure was determined by X-ray diffraction analysis and confirmed by the visible and IR spectra. The coordination number of the U atom is 8, with the hydroxyl O atom not involved in coordination with the metal ion. The main structural constituents of the compound are [(UO2)(C7H5O3)3]− anions formed by the sixcoordinate uranyl ion and three hydroxybenzoate ions acting as bidentate ligands. The imidazolium cations participate in hydrogen bonding, linking the adjacent [(UO2)(C7H5O3)3]− anions. The compound contains water molecules of crystallization, also participating in H bonding. More... »

PAGES

145-149

Journal

TITLE

Radiochemistry

ISSUE

2

VOLUME

56

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362214020039

DOI

http://dx.doi.org/10.1134/s1066362214020039

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029020673


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Levtsova", 
        "givenName": "A. A.", 
        "id": "sg:person.010643712271.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010643712271.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Andreev", 
        "givenName": "G. B.", 
        "id": "sg:person.01025137037.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025137037.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Budantseva", 
        "givenName": "N. A.", 
        "id": "sg:person.01073252237.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01073252237.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Mayak Production Association, pr. Lenina 31, 456780, Ozersk, Chelyabinsk oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tananaev", 
        "givenName": "I. G.", 
        "id": "sg:person.01141365437.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01141365437.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, 119071, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Myasoedov", 
        "givenName": "B. F.", 
        "id": "sg:person.01207500637.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1066362210040041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000836913", 
          "https://doi.org/10.1134/s1066362210040041"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1066362210040041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000836913", 
          "https://doi.org/10.1134/s1066362210040041"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.58.938", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009627231"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1066362212040042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026139462", 
          "https://doi.org/10.1134/s1066362212040042"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1066362212020014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044565582", 
          "https://doi.org/10.1134/s1066362212020014"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.saa.2010.01.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050245521"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.431384", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058009416"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1366/0003702944027660", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065263876"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1366/0003702944027660", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065263876"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1515/znb-2002-0307", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1104090927"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-03", 
    "datePublishedReg": "2014-03-01", 
    "description": "A new U(VI) compound with m-hydroxybenzoic acid, HIm[(UO2)(C7H5O3)3]\u00b72H2O, was prepared. Its structure was determined by X-ray diffraction analysis and confirmed by the visible and IR spectra. The coordination number of the U atom is 8, with the hydroxyl O atom not involved in coordination with the metal ion. The main structural constituents of the compound are [(UO2)(C7H5O3)3]\u2212 anions formed by the sixcoordinate uranyl ion and three hydroxybenzoate ions acting as bidentate ligands. The imidazolium cations participate in hydrogen bonding, linking the adjacent [(UO2)(C7H5O3)3]\u2212 anions. The compound contains water molecules of crystallization, also participating in H bonding.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1066362214020039", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1345524", 
        "issn": [
          "1066-3622", 
          "1608-3288"
        ], 
        "name": "Radiochemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "name": "Uranium(VI) complex with m-hydroxybenzoic acid. Synthesis, crystal structure, and spectral properties", 
    "pagination": "145-149", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "8a3fa006a0e85941850ecc224ddf951d604709fdbfc3a5c7195bd2756998ac4c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1066362214020039"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1029020673"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1066362214020039", 
      "https://app.dimensions.ai/details/publication/pub.1029020673"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:58", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1066362214020039"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1066362214020039'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1066362214020039'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1066362214020039'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1066362214020039'


 

This table displays all metadata directly associated to this object as RDF triples.

121 TRIPLES      21 PREDICATES      36 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1066362214020039 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N0c666e90bdcd4d4ab3cfc94c0f7aa5ea
4 schema:citation sg:pub.10.1134/s1066362210040041
5 sg:pub.10.1134/s1066362212020014
6 sg:pub.10.1134/s1066362212040042
7 https://doi.org/10.1016/j.saa.2010.01.012
8 https://doi.org/10.1063/1.431384
9 https://doi.org/10.1107/s0108767307043930
10 https://doi.org/10.1246/bcsj.58.938
11 https://doi.org/10.1366/0003702944027660
12 https://doi.org/10.1515/znb-2002-0307
13 schema:datePublished 2014-03
14 schema:datePublishedReg 2014-03-01
15 schema:description A new U(VI) compound with m-hydroxybenzoic acid, HIm[(UO2)(C7H5O3)3]·2H2O, was prepared. Its structure was determined by X-ray diffraction analysis and confirmed by the visible and IR spectra. The coordination number of the U atom is 8, with the hydroxyl O atom not involved in coordination with the metal ion. The main structural constituents of the compound are [(UO2)(C7H5O3)3]− anions formed by the sixcoordinate uranyl ion and three hydroxybenzoate ions acting as bidentate ligands. The imidazolium cations participate in hydrogen bonding, linking the adjacent [(UO2)(C7H5O3)3]− anions. The compound contains water molecules of crystallization, also participating in H bonding.
16 schema:genre research_article
17 schema:inLanguage en
18 schema:isAccessibleForFree false
19 schema:isPartOf Nba61b52b36e24e9bb8874f79843edb6a
20 Ne828fca49d5f46cd9b21a02f2435bebe
21 sg:journal.1345524
22 schema:name Uranium(VI) complex with m-hydroxybenzoic acid. Synthesis, crystal structure, and spectral properties
23 schema:pagination 145-149
24 schema:productId N0e2cb76a6845459781994bce4d404773
25 N6392a973ff7940c881a9a1346d3609a5
26 Nda75614595e748e98bc95f3a9af9b143
27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029020673
28 https://doi.org/10.1134/s1066362214020039
29 schema:sdDatePublished 2019-04-11T01:58
30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
31 schema:sdPublisher N62824819d1be4e36bfddd9d8046f350e
32 schema:url http://link.springer.com/10.1134%2FS1066362214020039
33 sgo:license sg:explorer/license/
34 sgo:sdDataset articles
35 rdf:type schema:ScholarlyArticle
36 N0c666e90bdcd4d4ab3cfc94c0f7aa5ea rdf:first sg:person.010643712271.64
37 rdf:rest Nb58b95079c504c80902e56aa74cb9cf8
38 N0e2cb76a6845459781994bce4d404773 schema:name readcube_id
39 schema:value 8a3fa006a0e85941850ecc224ddf951d604709fdbfc3a5c7195bd2756998ac4c
40 rdf:type schema:PropertyValue
41 N62824819d1be4e36bfddd9d8046f350e schema:name Springer Nature - SN SciGraph project
42 rdf:type schema:Organization
43 N6392a973ff7940c881a9a1346d3609a5 schema:name doi
44 schema:value 10.1134/s1066362214020039
45 rdf:type schema:PropertyValue
46 N734a1674d75f45f681f854029d8fbbe3 rdf:first sg:person.01207500637.58
47 rdf:rest rdf:nil
48 Nb58b95079c504c80902e56aa74cb9cf8 rdf:first sg:person.01025137037.12
49 rdf:rest Nd827205231c342ca9244e4174fac3509
50 Nba61b52b36e24e9bb8874f79843edb6a schema:issueNumber 2
51 rdf:type schema:PublicationIssue
52 Nbcb5d77ee65443168a3675aa2d2c956f rdf:first sg:person.01141365437.25
53 rdf:rest N734a1674d75f45f681f854029d8fbbe3
54 Nd3a966031b604149a9d32ce955674bb7 schema:name Mayak Production Association, pr. Lenina 31, 456780, Ozersk, Chelyabinsk oblast, Russia
55 rdf:type schema:Organization
56 Nd827205231c342ca9244e4174fac3509 rdf:first sg:person.01073252237.09
57 rdf:rest Nbcb5d77ee65443168a3675aa2d2c956f
58 Nda75614595e748e98bc95f3a9af9b143 schema:name dimensions_id
59 schema:value pub.1029020673
60 rdf:type schema:PropertyValue
61 Ne828fca49d5f46cd9b21a02f2435bebe schema:volumeNumber 56
62 rdf:type schema:PublicationVolume
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
67 schema:name Inorganic Chemistry
68 rdf:type schema:DefinedTerm
69 sg:journal.1345524 schema:issn 1066-3622
70 1608-3288
71 schema:name Radiochemistry
72 rdf:type schema:Periodical
73 sg:person.01025137037.12 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
74 schema:familyName Andreev
75 schema:givenName G. B.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025137037.12
77 rdf:type schema:Person
78 sg:person.010643712271.64 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
79 schema:familyName Levtsova
80 schema:givenName A. A.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010643712271.64
82 rdf:type schema:Person
83 sg:person.01073252237.09 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
84 schema:familyName Budantseva
85 schema:givenName N. A.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01073252237.09
87 rdf:type schema:Person
88 sg:person.01141365437.25 schema:affiliation Nd3a966031b604149a9d32ce955674bb7
89 schema:familyName Tananaev
90 schema:givenName I. G.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01141365437.25
92 rdf:type schema:Person
93 sg:person.01207500637.58 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
94 schema:familyName Myasoedov
95 schema:givenName B. F.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58
97 rdf:type schema:Person
98 sg:pub.10.1134/s1066362210040041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000836913
99 https://doi.org/10.1134/s1066362210040041
100 rdf:type schema:CreativeWork
101 sg:pub.10.1134/s1066362212020014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044565582
102 https://doi.org/10.1134/s1066362212020014
103 rdf:type schema:CreativeWork
104 sg:pub.10.1134/s1066362212040042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026139462
105 https://doi.org/10.1134/s1066362212040042
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/j.saa.2010.01.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050245521
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1063/1.431384 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058009416
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1246/bcsj.58.938 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009627231
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1366/0003702944027660 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065263876
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1515/znb-2002-0307 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104090927
118 rdf:type schema:CreativeWork
119 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
120 schema:name Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, 119071, Moscow, Russia
121 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...