Preparation of Np, Pu, and U dioxides in nitric acid solutions in the presence of hydrazine hydrate View Full Text


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Article Info

DATE

2013-11

AUTHORS

B. F. Myasoedov, Yu. M. Kulyako, A. M. Fedoseev, A. A. Bessonov, T. I. Trofimov, S. A. Perevalov, S. E. Vinokurov, M. D. Samsonov, A. Yu. Shadrin

ABSTRACT

Heating of nitric acid solutions of Np and Pu (∼90°C) in the presence of hydrazine hydrate (HH) leads to the formation of their hydrated dioxides in solution, transforming into crystalline dioxides at 300°C. Thermolysis of a mixed solution of U, Np, and Pu nitrates under the same conditions initially yields hydrated (U,Np,Pu)O2·nH2O, which on heating in air to ∼300°C transforms into a crystalline solid solution of (U,Np,Pu)O2. This method for stabilization of U dioxide in the presence of Pu in an oxidizing atmosphere can be used for preparing (U,Pu)O2 solid solutions of variable composition. This procedure shows doubtless prospects as a simple, efficient, and relatively low-temperature method for the production of MOX fuel for fast reactors. More... »

PAGES

574-580

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362213060027

DOI

http://dx.doi.org/10.1134/s1066362213060027

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000988717


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