Ontology type: schema:ScholarlyArticle
2013-11
AUTHORSB. F. Myasoedov, Yu. M. Kulyako, A. M. Fedoseev, A. A. Bessonov, T. I. Trofimov, S. A. Perevalov, S. E. Vinokurov, M. D. Samsonov, A. Yu. Shadrin
ABSTRACTHeating of nitric acid solutions of Np and Pu (∼90°C) in the presence of hydrazine hydrate (HH) leads to the formation of their hydrated dioxides in solution, transforming into crystalline dioxides at 300°C. Thermolysis of a mixed solution of U, Np, and Pu nitrates under the same conditions initially yields hydrated (U,Np,Pu)O2·nH2O, which on heating in air to ∼300°C transforms into a crystalline solid solution of (U,Np,Pu)O2. This method for stabilization of U dioxide in the presence of Pu in an oxidizing atmosphere can be used for preparing (U,Pu)O2 solid solutions of variable composition. This procedure shows doubtless prospects as a simple, efficient, and relatively low-temperature method for the production of MOX fuel for fast reactors. More... »
PAGES574-580
http://scigraph.springernature.com/pub.10.1134/s1066362213060027
DOIhttp://dx.doi.org/10.1134/s1066362213060027
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