Extraction properties of 1,7-Bis(dibutylcarbamoyl)-1,7-bis(diphenylphosphinyl)heptane View Full Text


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Article Info

DATE

2012-09

AUTHORS

A. N. Turanov, V. K. Karandashev, A. N. Yarkevich

ABSTRACT

Extraction of microamounts of U(VI), Th(IV), and REE(III) from HNO3 solutions in the form of complexes with 1,7-bis(dibutylcarbamoyl)-1,7-bis(diphenylphosphinyl)heptane (I) was studied. The influence of the composition of the aqueous and organic phases on the extraction efficiency was considered, and the stoichiometry of the extractable complexes was determined. The extraction of metal ions is considerably enhanced in the presence of an ionic liquid. In neutral media, compound I exhibits higher extraction ability than does its mono analog, (dibutylcarbamoylmethyl)diphenylphosphine oxide (II). More... »

PAGES

477-482

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362212050104

DOI

http://dx.doi.org/10.1134/s1066362212050104

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024528839


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