An X-ray photoelectron study of the interaction of uranyl group with sulfosuccinyl chitosan View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-04-04

AUTHORS

I. E. Veleshko, A. N. Veleshko, A. Yu. Teterin, K. I. Maslakov, Yu. A. Teterin, K. E. Ivanov, E. V. Rumyantseva, A. N. Levov, V. P. Varlamov

ABSTRACT

Interaction of uranium with low-molecular-weight sulfosuccinyl chitosan (SSLMWC) from sulfate solutions was studied by X-ray photoelectron spectroscopy. The interaction involves formation of complexes with the uranyl group on the SSLMWC surface. The equatorial plane of these complexes can contain nitrogen atom of the amino group and oxygen atoms of the sulfato and sulfo groups SO42− and -SO3H, carboxy groups, and free hydroxy groups. On keeping the complex in a vacuum, two chemically nonequivalent states of U ions, U4+ and UO22+, are observed. The U4+ formation in solid U-containing samples of chitosan and SSLMWC is attributed to the radical reaction of the UO22+ reduction with the primary hydroxy group of chitosan in a vacuum of the spectrometer under the action of X-ray radiation. More... »

PAGES

122-127

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362212020038

DOI

http://dx.doi.org/10.1134/s1066362212020038

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051718033


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