Ontology type: schema:ScholarlyArticle
2010-08
AUTHORSA. A. Levtsova, G. B. Andreev, N. A. Budantseva, I. G. Tananaev, B. F. Myasoedov
ABSTRACTA new complex compound of U(VI) with m-hydroxybenzoic acid, K[(UO2)(C7H5O3)3]·5H2O, was prepared and characterized. A single crystal X-ray diffraction study showed that the coordination polyhedron of the U atom is a hexagonal bipyramid whose equatorial plane is formed by the O atoms of carboxy groups of three anions of m-hydroxybenzoic acid. The K atoms act as outer-sphere cations linking the adjacent anions [UO2(C7H5O3)3]− into neutral dimers {[UO2(C7H5O3)3]K(H2O)3}2. The structure also contains water molecules of crystallization, retained by hydrogen bonds. More... »
PAGES354-357
http://scigraph.springernature.com/pub.10.1134/s1066362210040041
DOIhttp://dx.doi.org/10.1134/s1066362210040041
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