Ontology type: schema:ScholarlyArticle
2008-04
AUTHORSG. F. Egorov, E. V. Belova, G. P. Tkhorzhnitskii, I. G. Tananaev, E. R. Nazin, G. M. Zachinyaev
ABSTRACTThe kinetics of thermochemical reaction of 30% TBP in hexachlorobutadiene (HCBD) saturated with HNO3 (1.35 M HNO3) in two-phase systems with 12 M HNO3 at temperatures from 90 to 115°C was studied. The kinetic parameters of thermolysis of organic solutions of TBP in HCBD, contacting with HNO3 in open and closed vessels, were determined experimentally for the subsequent estimation of the explosion hazard of these systems under conditions of extraction recovery of high-level radioactive materials. It was shown that, in two-phase systems, solutions of TBP in HCBD exhibit increased resistance to thermochemical oxidation with nitric acid in comparison with hydrocarbon solutions of the extractant in the entire temperature range. More... »
PAGES171-175
http://scigraph.springernature.com/pub.10.1134/s1066362208020148
DOIhttp://dx.doi.org/10.1134/s1066362208020148
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1005712842
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Egorov",
"givenName": "G. F.",
"id": "sg:person.014075127401.67",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014075127401.67"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Belova",
"givenName": "E. V.",
"id": "sg:person.010731245602.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010731245602.23"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Tkhorzhnitskii",
"givenName": "G. P.",
"id": "sg:person.014363320653.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014363320653.16"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Tananaev",
"givenName": "I. G.",
"id": "sg:person.01141365437.25",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01141365437.25"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Scientific and Technical Center of Nuclear and Radiation Safety, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Nazin",
"givenName": "E. R.",
"id": "sg:person.014742341211.27",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014742341211.27"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Scientific and Technical Center of Nuclear and Radiation Safety, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Zachinyaev",
"givenName": "G. M.",
"id": "sg:person.010772414115.98",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010772414115.98"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf01123537",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006436101",
"https://doi.org/10.1007/bf01123537"
],
"type": "CreativeWork"
}
],
"datePublished": "2008-04",
"datePublishedReg": "2008-04-01",
"description": "The kinetics of thermochemical reaction of 30% TBP in hexachlorobutadiene (HCBD) saturated with HNO3 (1.35 M HNO3) in two-phase systems with 12 M HNO3 at temperatures from 90 to 115\u00b0C was studied. The kinetic parameters of thermolysis of organic solutions of TBP in HCBD, contacting with HNO3 in open and closed vessels, were determined experimentally for the subsequent estimation of the explosion hazard of these systems under conditions of extraction recovery of high-level radioactive materials. It was shown that, in two-phase systems, solutions of TBP in HCBD exhibit increased resistance to thermochemical oxidation with nitric acid in comparison with hydrocarbon solutions of the extractant in the entire temperature range.",
"genre": "research_article",
"id": "sg:pub.10.1134/s1066362208020148",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1345524",
"issn": [
"1066-3622",
"1608-3288"
],
"name": "Radiochemistry",
"type": "Periodical"
},
{
"issueNumber": "2",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "50"
}
],
"name": "Kinetics of thermochemical reaction of TBP solutions in HCBD with nitric acid in two-phase systems",
"pagination": "171-175",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"1b3802240ff89cb03d0391e74a56330ce28c3f40a79df5caa66ce93b35ed3dfc"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1066362208020148"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1005712842"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1066362208020148",
"https://app.dimensions.ai/details/publication/pub.1005712842"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T19:55",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000503.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1134%2FS1066362208020148"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1066362208020148'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1066362208020148'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1066362208020148'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1066362208020148'
This table displays all metadata directly associated to this object as RDF triples.
104 TRIPLES
21 PREDICATES
28 URIs
19 LITERALS
7 BLANK NODES