Structure of the double formate KNpO2(OOCH)2 View Full Text


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Article Info

DATE

2008-02

AUTHORS

I. A. Charushnikova, N. N. Krot, Z. A. Starikova, F. M. Dolgushin, I. N. Polyakova

ABSTRACT

KNpO2(OOCH)2 was isolated from neutral Np(V) solutions with a high concentration of potassium formate. The crystal structure of this compound was determined. The structure consists of infinite anionic chains [NpO2(OOCH)2]nn−. Potassium cations are located between these chains. The Np coordination polyhedron is a hexagonal bipyramid whose equatorial plane is formed by the oxygen atoms of four HCOO− ions. The Np bipyramids in the chains are bound via common equatorial edges. The anionic chains in the structures of KNpO2(OOCH)2 and NH4NpO2(OOCH)2 studied previously have similar composition but different structure. More... »

PAGES

34-37

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362208010049

DOI

http://dx.doi.org/10.1134/s1066362208010049

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040605646


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