Crystal structure of a double Np(V) ammonium propionate, NH4[(NpO2)3(C2H5COO)4(H2O)]·3H2O View Full Text


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Article Info

DATE

2006-01

AUTHORS

M. S. Grigor’ev, M. Yu. Antipin, N. N. Krot

ABSTRACT

The structure of NH4[(NpO2)3(C2H5COO)4(H2O)]·3H2O was studied by single crystal X-ray diffraction. The single crystals were prepared by hydrothermal synthesis. In the structure, there are three crystallographically independent Np atoms with different equatorial surrounding. All of them have CN 7; the coordination polyhedron is a distorted pentagonal bipyramid. Each NpO2+ cation is bonded to four other cations, acting simultaneously as a bidentate ligand and a coordination center for two other dioxocations. The cation-cation interactions result in formation of trigonal-hexagonal cationic networks. More... »

PAGES

6-10

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1066362206010024

DOI

http://dx.doi.org/10.1134/s1066362206010024

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028258899


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