A New Approach to the Justification of the Wolkenstein–Ptitsyn Formula for the Parameter of the Vitrification Equation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

D. S. Sanditov, V. V. Mantatov

ABSTRACT

An extended interpretation of the Wolkenstein–Ptitsyn formula for temperature band δTg, characterizing a range of transition from liquid to glass, is considered using the Razumovskaya–Bartenev concept. The derivation of this formula proposed by the authors does not depend on the specific type of temperature dependence of relaxation time. For silicate glasses, calculation δTg by this formula agrees with the calculation by the Williams–Landel–Ferry relation and with the left side of glass transition equation qτg = δTg, where q is the cooling rate and τg is relaxation time. Based on the experimental data, the calculation of parameters of the Razumovskaya–Bartenev equation for silicate glasses and amorphous polymers is carried out for the first time. More... »

PAGES

1749-1754

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063784218120174

DOI

http://dx.doi.org/10.1134/s1063784218120174

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111750254


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