Ontology type: schema:ScholarlyArticle Open Access: True
2017-06-11
AUTHORSV. Yu. Osipov, F. M. Shakhov, N. N. Efimov, V. V. Minin, S. V. Kidalov, A. Ya. Vul’
ABSTRACTDiamond single crystals synthesized from powder detonation nanodiamonds (DNDs) by means of treatment at high pressures (P ~ 7 GPa) and temperatures (T > 1300°C) have been studied by electron paramagnetic resonance (EPR). A key feature of treatment (high-pressure high–temperature (HPHT) sintering) is the use of low molecular weight alcohols in the process. The appearance of a hyperfine EPR signal structure due to “paramagnetic nitrogen” (P1 centers) is explained by the growth of submicron and micron diamond single crystals from DND nanocrystals by the oriented attachment and coalescence mechanism. Such growth and coarsening of crystals appreciably decreases the concentration of paramagnetic centers, the presence of which hinders the detection of a hyperfine structure in the EPR signal from P1 centers, in the near-surface areas of coalesced and grown together DND particles. It has been shown that the concentration of paramagnetic defects of all types decreases to ~3.1 × 1018 g–1 (~60 ppm) during HPHT treatment at T = 1650°C. This causes the successful identification of P1 centers, whose fraction is no less than ~40% of the total amount of paramagnetic centers in microcrystals synthesized by HPHT sintering. More... »
PAGES1146-1153
http://scigraph.springernature.com/pub.10.1134/s1063783417060191
DOIhttp://dx.doi.org/10.1134/s1063783417060191
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1085966680
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0203",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Classical Physics",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0204",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Condensed Matter Physics",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0206",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Quantum Physics",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Osipov",
"givenName": "V. Yu.",
"id": "sg:person.011737110415.43",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011737110415.43"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Shakhov",
"givenName": "F. M.",
"id": "sg:person.010775023623.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010775023623.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Leninskii pr. 31, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Efimov",
"givenName": "N. N.",
"id": "sg:person.01024204401.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01024204401.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Leninskii pr. 31, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Minin",
"givenName": "V. V.",
"id": "sg:person.011207441575.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Kidalov",
"givenName": "S. V.",
"id": "sg:person.016676653323.01",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016676653323.01"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Politekhnicheskaya ul. 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Vul\u2019",
"givenName": "A. Ya.",
"id": "sg:person.014132507145.02",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014132507145.02"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1134/s0020168516040142",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015232507",
"https://doi.org/10.1134/s0020168516040142"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-3-662-04548-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006004391",
"https://doi.org/10.1007/978-3-662-04548-0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1063785017010084",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1083912604",
"https://doi.org/10.1134/s1063785017010084"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s00723-010-0158-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034253122",
"https://doi.org/10.1007/s00723-010-0158-4"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0021364009080074",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003240107",
"https://doi.org/10.1134/s0021364009080074"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-06-11",
"datePublishedReg": "2017-06-11",
"description": "Diamond single crystals synthesized from powder detonation nanodiamonds (DNDs) by means of treatment at high pressures (P ~ 7 GPa) and temperatures (T > 1300\u00b0C) have been studied by electron paramagnetic resonance (EPR). A key feature of treatment (high-pressure high\u2013temperature (HPHT) sintering) is the use of low molecular weight alcohols in the process. The appearance of a hyperfine EPR signal structure due to \u201cparamagnetic nitrogen\u201d (P1 centers) is explained by the growth of submicron and micron diamond single crystals from DND nanocrystals by the oriented attachment and coalescence mechanism. Such growth and coarsening of crystals appreciably decreases the concentration of paramagnetic centers, the presence of which hinders the detection of a hyperfine structure in the EPR signal from P1 centers, in the near-surface areas of coalesced and grown together DND particles. It has been shown that the concentration of paramagnetic defects of all types decreases to ~3.1 \u00d7 1018 g\u20131 (~60 ppm) during HPHT treatment at T = 1650\u00b0C. This causes the successful identification of P1 centers, whose fraction is no less than ~40% of the total amount of paramagnetic centers in microcrystals synthesized by HPHT sintering.",
"genre": "article",
"id": "sg:pub.10.1134/s1063783417060191",
"isAccessibleForFree": true,
"isPartOf": [
{
"id": "sg:journal.1430954",
"issn": [
"1063-7834",
"1090-6460"
],
"name": "Physics of the Solid State",
"publisher": "Pleiades Publishing",
"type": "Periodical"
},
{
"issueNumber": "6",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "59"
}
],
"keywords": [
"diamond single crystals",
"near-surface area",
"high pressure",
"HPHT sintering",
"detonation nanodiamonds",
"coalescence mechanism",
"diamond crystallites",
"sintering",
"low molecular weight alcohols",
"signal structure",
"single crystals",
"temperature",
"weight alcohols",
"paramagnetic defects",
"HPHT treatment",
"coarsening",
"submicron",
"nanodiamonds",
"electron paramagnetic resonance",
"pressure",
"nanocrystals",
"crystallites",
"crystals",
"growth of submicron",
"structure",
"paramagnetic nitrogen",
"key features",
"signals",
"total amount",
"paramagnetic centers",
"microcrystals",
"process",
"concentration",
"paramagnetic resonance",
"paramagnetic nitrogen centers",
"defects",
"nitrogen",
"amount",
"fraction",
"such growth",
"resonance",
"growth",
"detection",
"means",
"area",
"P1 centers",
"attachment",
"use",
"features",
"mechanism",
"types",
"center",
"successful identification",
"presence",
"identification",
"means of treatment",
"treatment",
"alcohol",
"appearance",
"EPR signal",
"hyperfine structure",
"nitrogen centers"
],
"name": "Identification of paramagnetic nitrogen centers (P1) in diamond crystallites synthesized via the sintering of detonation nanodiamonds at high pressure and temperature",
"pagination": "1146-1153",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1085966680"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1063783417060191"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1063783417060191",
"https://app.dimensions.ai/details/publication/pub.1085966680"
],
"sdDataset": "articles",
"sdDatePublished": "2022-11-24T21:02",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_715.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1134/s1063783417060191"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1063783417060191'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1063783417060191'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1063783417060191'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1063783417060191'
This table displays all metadata directly associated to this object as RDF triples.
185 TRIPLES
21 PREDICATES
93 URIs
78 LITERALS
6 BLANK NODES