Manganese Clusterization in ZnS:Mn, Mg Synthesized by Self-Propagating High-Temperature Synthesis View Full Text


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Article Info

DATE

2020-03

AUTHORS

Yu. Yu. Bacherikov, I. P. Vorona, O. B. Okhrimenko, V. P. Kladko, A. G. Zhuk, S. M. Okulov, Yu. O. Polishchuk, A. V. Gilchuk, Yu. M. Romanenko, V. V. Kidalov

ABSTRACT

The ZnS:Mn, Mg powder is fabricated by self-propagating high-temperature synthesis with the simultaneous introduction of Mn and Mg impurities. It is found that the simultaneous introduction of Mn and Mg impurities leads to the nonuniform distribution of manganese forming regions with a lower and higher Mn concentration. In the latter case, the manganese ions form paramagnetic clusters. At the same time, numerous centers of self-activated luminescence form in the synthesized ZnS:Mn, Mg due to mechanical stress and lattice strain. Additional annealing leads to a more uniform Mn distribution in the formed ZnS:Mn, Mg phosphor, which is accompanied by an increase in the intensity of the manganese photoluminescence band and quenching of the self-activated luminescence band. More... »

PAGES

330-336

References to SciGraph publications

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  • 2000-03. Excitation spectra and structure of luminescence centers of manganese ions in single crystals of zinc sulfide in JOURNAL OF APPLIED SPECTROSCOPY
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  • 1999-01. Electroluminescence from ZnS:MnCl2 thin film devices co-doped with MgF2 or MgS in MATERIALS RESEARCH INNOVATIONS
  • 2000. Atom, Molecule, and Cluster Beams II, Cluster Beams, Fast and Slow Beams, Accessory Equipment and Applications in NONE
  • 2002-11. Intracenter transitions of iron-group ions in II–VI semiconductor matrices in PHYSICS OF THE SOLID STATE
  • 2001-01. A study of luminescence centers related to copper and oxygen in ZnSe in SEMICONDUCTORS
  • 2017-02-27. Structural and optical properties of ZnS:Mn micro-powders, synthesized from the charge with a different Zn/S ratio in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
  • 2005-11. Mechanism of photoluminescence excitation of Mn2+ ions in ZnS crystals in JOURNAL OF APPLIED SPECTROSCOPY
  • 2005-05. The effect of oxygen on the ZnS electronic energy-band structure in SEMICONDUCTORS
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    http://scigraph.springernature.com/pub.10.1134/s1063782620030033

    DOI

    http://dx.doi.org/10.1134/s1063782620030033

    DIMENSIONS

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