CNT-Based Label-Free Electrochemical Sensing of Native DNA with Allele Single Nucleotide Polymorphism View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

H. V. Grushevskaya, N. G. Krylova, I. V. Lipnevich, A. S. Babenka, V. P. Egorova, R. F. Chakukov

ABSTRACT

A label-free high-performance electrochemical sensing of single nucleotide polymorphism in native genomic DNA samples from cancer tissues, in oncogene-specific complementary DNA and in amplicons has been carried out on bundles of few-walled carboxylated carbon nanotubes, surface of which was coated with electron-dense layer of probe DNA. High selectivity and sensitivity of the novel DNA-nanosensor are ensured by the following features. Firstly, a complementary-hybridization signal is enhanced by resonance between plasmons in carbon nanotubes and dipole oscillations of hydrated nucleic acids located in near-electrode Helmholtz double layer of the impedance sensor. Secondly, a decoration of carbon nanotubes by adhered metal atoms in a high-spin state leads to Fermi level stabilization for the carbon nanotube bundles. More... »

PAGES

1836-1838

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063782618140117

DOI

http://dx.doi.org/10.1134/s1063782618140117

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110933738


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