Study of the effect of the acid-base surface properties of ZnO, Fe2O3 and ZnFe2O4 oxides on their gas sensitivity to ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

S. S. Karpova, V. A. Moshnikov, A. I. Maksimov, S. V. Mjakin, N. E. Kazantseva

ABSTRACT

Binary (ZnO, Fe2O3) and ternary (ZnFe2O4) gas-sensitive oxide materials are synthesized, and the correlation between their sensitivity to ethanol vapor and the functional chemical composition of the surface is studied by X-ray photoelectron spectroscopy and by the technique of the adsorption of acid-base indicators. It is found that the sensitivity to ethanol increases with increasing content of Brönsted acid sites with the acidity index pKa ≈ 2.5 and with increasing percentage of surface oxygen involved in OH/CO3/C-O groups. This interrelation is attributed to the specific features of interaction between ethanol molecules and hydroxyl groups on the surface of the oxides. More... »

PAGES

1026-1030

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063782613080095

DOI

http://dx.doi.org/10.1134/s1063782613080095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043851757


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