X-ray natural circular dichroism in copper metaborate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07

AUTHORS

E. N. Ovchinnikova, A. Rogalev, F. Wilhelm, K. A. Kozlovskaya, A. P. Oreshko, V. E. Dmitrienko

ABSTRACT

The local electronic structure of copper ions in a copper metaborate CuB2O4 crystal is studied on the ESRF synchrotron using X-ray absorption polarization-dependent spectroscopy. The X-ray natural circular dichroism near the K absorption edge of copper is measured in the direction that is perpendicular to crystal axis c. The data obtained indicate the presence of hybridized p–d electronic states of copper. Theoretical calculations are used to separate the contributions of the two crystallographically nonequivalent positions of copper atoms in the unit cell of CuB2O4 to the absorption and X-ray circular dichroism spectra of the crystal. More... »

PAGES

27-32

References to SciGraph publications

  • 2003-08. X-ray optical activity: Applications of sum rules in JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS
  • 2008-05. Investigation of X-ray natural circular dichroism in a CsCuCl3 single crystal: Theory and experiment in CRYSTALLOGRAPHY REPORTS
  • 2012-06-15. Resonant X-ray diffraction: Basic theoretical principles in THE EUROPEAN PHYSICAL JOURNAL SPECIAL TOPICS
  • 1998-07. Calculation of X-ray natural circular dichroism in THE EUROPEAN PHYSICAL JOURNAL B
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s1063776116050186

    DOI

    http://dx.doi.org/10.1134/s1063776116050186

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