Magnetism of palladium clusters in nanoporous carbon View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-10

AUTHORS

B. D. Shanina, A. M. Danishevskii, A. I. Veinger, A. A. Sitnikova, R. N. Kyutt, A. V. Shchukarev, S. K. Gordeev

ABSTRACT

To determine the electronic properties of metal-carbon clusters, palladium clusters are introduced into nanoporous carbon samples. The structural and magnetic properties of the nanocomposite thus obtained are investigated. A ferromagnetic resonance (FMR) component is observed in the electron spin resonance (ESR) spectra measured in a wide temperature range. The electron density of states (DOS) of clusters consisting of a palladium atom surrounded by carbon atoms is calculated, and it is shown that, due to the interaction between electronic terms of carbon and metal, such a cluster should exhibit magnetism. The investigation of the structures of the porous skeleton of nanoporous carbon and of palladium clusters has allowed us to reveal how carbon and palladium atoms are brought into close contact so that to give rise to the observed ferromagnetism. More... »

PAGES

609

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063776109100070

DOI

http://dx.doi.org/10.1134/s1063776109100070

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000617195


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