Deformation Mechanism of the LOSOD-Type Framework in Minerals of Bystrite Subgroup with a Change in Temperature and Chemical Composition View Full Text


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Article Info

DATE

2018-12

AUTHORS

A. N. Sapozhnikov, E. V. Kaneva

ABSTRACT

A Low-temperature (100 K) analysis of the crystalline structures of Cl-bystrite and sulfhydrylbystrite has been carried out, and the data obtained have been compared with the room-temperature characteristics of these minerals. The framework deformations are considered as a result of change in the ditrigonality of six-membered tetrahedral rings: the decrease in the unit-cell volume at low temperature is determined mainly by the increase in the ditrigonality (compression) of six-membered framework rings. Oblique and vertical (corrugated) rings are distorted to a greater extent than horizontal rings. The deformation mechanisms is shown to be the same for the frameworks of bystrite-subgroup minerals and the sodalite framework. More... »

PAGES

1099-1103

References to SciGraph publications

Journal

TITLE

Crystallography Reports

ISSUE

7

VOLUME

63

From Grant

  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1063774518070210

    DOI

    http://dx.doi.org/10.1134/s1063774518070210

    DIMENSIONS

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