Synthesis, Crystal Structure, and Luminescent Properties of Ag(I) Coordination Polymer with Tricarboxylic Acid and Flexible N-donor Ligand View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-12

AUTHORS

J. F. Lu, Y. H. Xu, P. A. Li, L. X. Jin, C. B. Zhao, X. H. Guoand, H. G. Ge

ABSTRACT

The reaction of AgNO3 with combinations of 1,3-bis(4-pyridyl)propane (bpp) and 1,3,5-benzenetricarboxylic acid (H3btc) in aqueous alcohol/ammonia at room temperature produces crystals of {[Ag6(H2O)2(bpp)6] · (btc)2 · 25H2O}n (Ι). Single crystal X-ray diffraction analysis reveals that the complex Ι consists of 1D infinite cationic chains of [Ag(bpp)]nn+ and [Ag(H2O)(bpp)]nn+ which are further linked into the cation layer of [Ag(bpp)]nn+ by Ag···π interactions. The noncoordinated btc3− serves as template driving surrounding water molecules to aggregate into the anionic water layer. The neighboring anionic water layer and cationic layer were further alternately joined into a 3D sandwich-like framework by hydrogen bonding. In addition, the luminescent properties of Ι were investigated. More... »

PAGES

1046-1050

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774517070173

DOI

http://dx.doi.org/10.1134/s1063774517070173

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101219430


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