Crystal structure of chlorinated mineral of cancrinite group with bystrite-type framework View Full Text


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Article Info

DATE

2017-07

AUTHORS

E. V. Kaneva, A. N. Sapozhnikov, L. F. Suvorova

ABSTRACT

The formula of chlorinated bystrite (rare mineral of cancrinite group) has been refined to Na7.22Ca0.92[Al6Si6O24](S5)0.94Cl1.01. The X-ray diffraction data on the contents of chlorine and sulfur in this mineral are confirmed by the results of chemical analysis. The bystrite cage is found to contain a (S5)2–cluster, which is elongated along the c axis and has a chain configuration. Different ways of aggregation of sulfur atoms lead to cis- and trans-configurations of chains. Columns of cancrinite cages contain–Ca–Cl–Ca–Cl–chains, which were observed previously in the structures of minerals of davyne subgroup, afghanite, and tounkite. More... »

PAGES

558-565

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774517040071

DOI

http://dx.doi.org/10.1134/s1063774517040071

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090938597


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